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Properties of polymers essay
Polymers description 1000 words
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Polymer modified binders:
First, understanding the basics of polymers. Polymers are very large molecules formed by combining many smaller molecules together chemically. The starting molecules of polymers is called monomer which on combination forms random co-polymers. Co-polymers like SBR are widely used as a modifier in asphalt mix. They are very widely used for preventive pavement maintenance technique in cold weather like in chip seals, slurry seal, cold recycled mix and micro-cracking.
There are basically two types of polymer used as a modifier, namely Plastomer and Elastomer. Plastomers polymers like ethylene vinyl acetate (EVA) have high rate of strength gain but shows brittle behaviour at low temperature. Elastomers like SBR and NR shows a very elastic behaviour, stretches to around ten times and quickly return to original shape upon release of stress. The process of modifying asphalt differs in both plastomers and elastomers. Plastomers forms a tough and rigid network while elastomers forms an elastic framework.
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Its advantage over other polymer modifier is its availability in emulsion which can be easily used when diluted with water. It also do not have any flammable solvents. PVA modified emulsion have shown increased compressive strength over neat mix in cold mix
Tests done for Polymer Modified Binders: Elastic Recovery Test: this test is widely used in the states of US and some other countries also. The test measures the degree of recovery upon release of stress. The test uses a ductilometer that elongates the asphalt specimen at constant rate. After some time, the specimen is cut and allowed to rest. The distance between the ends of the cut specimen is now measured. The elastic recovery is calculated as:
% recovery = (initial elongation-observed elongation after rejoining sample)/(initial
Doing so would cause the asphalt to harden and therefore make it unusable. “Because asphalt cannot be stored, it is not susceptible to being inventoried” (Justia, 2000).
Fig. 2(A) shows the phase diagrams of IPM, water, and surfactant mixtures at the ratios of 60:40, 65:35, and 70:30 (v/v), respectively. Fig. 2(B) shows the phase diagrams of ethyl oleate, water, and surfactant mixtures at ratios of 90:10, 95:5 and 100:0, respectively. Filled circles mean self-emulsifying points, and black areas represent the self-emulsifying regions. In other area, the compositions showed inverted emulsion, gel-like form, or phase-separation. In general, when the oil content in the oil and surfactant mixtures is ≤30%, the condition of the mixtures changed from water-in-oil emulsion to a clear gel-like form and then to microemulsion. Otherwise, the dispersions showed phase separation, this result was similar to the results previously studied by Guo et al. [16]. Our finding showed that IPM + surfactant mixture (65:35, v/v) and ethyl oleate + surfactant mixture (90:10, v/v) showed the most self-emulsifying regions (Fig. 2). Overall, in contrast to IPM + surfactant mixture (65:35, v/v), ethyl oleate + surfactant mixture (90:10, v/v) showed finer emulsion in larger self-emulsifying range. These results indicate that ethyl oleate and Tween 80:Carbitol (90:10, v/v) were identified as the optimal oil
Strength In terms of strength the effect the plasticizers have on the polymers is that the additive makes the polymer have a weak intermolecular force. As a result of this the polymers will be unstable an easier to handle. Due to this the polymer then can be remoulded and tougher and this will increase the polymers
Hydrocolloid dressings have been utilized in the midst of countless health care facilities due to the increasing number of decubitus ulcers. Decubitus ulcer, also commonly known as bedsores or pressure ulcers, is an exposed wound on your skin frequently occurring on the skin concealing bony areas. It is mutual among the elderly, people who devote prolonged periods of time in bed or a wheelchair, and individuals who cannot move particular body parts without assistance (Solan, 2014). Many diverse prevention dressings have been introduced across the years to diagnose pressure ulcers; this paper pursues to examine appropriate literature to evaluate and compare the efficacy of hydrocolloid dressing in patients with decubitus ulcers.
It is a kind of plastic that originates from consolidating ethylene (found in unrefined petroleum) and chlorine (found in salt). At the point when joined together these substances get to be Polyvinyl Chloride (PVC) gum, or as it is better known - Vinyl. It is then further handled to be made more adaptable, inflexible, semi-fluid, clear or bright, thick or thin.
Denture teeth can be made of acrylic poly(methyl methacrylate) (PMMA) or composite resins. PMMA is a polymer - a material made the from joining of methyl methacrylate monomers. Properties of PMMA include resistance to abrasion, chemical stability and a high boiling point. (Jun Shen et al. 2011). However, weak flexure and impact strength of PMMA are of concern as they account for denture failure. (Bolayir G, Boztug A and Soygun K. 2013). Composite denture teeth are made of a three distinct phases - filler, matrix and coupling agents. Out of the types of composite teeth available, nano-filled composite teeth are preferred. Composite teeth have a PMMA coating around the tooth and a high content of filler particles. This gives them strength, higher resistance to forces than acrylic teeth and provides compete polymerization due to the PMMA coating. (Anusavice, K. J., Phillips, R. W., Shen, C., & Rawls, H. R, 2012). If the interface between the PMMA denture base and PMMA or composite teeth was weak, the denture will not be able to sustain occlusal forces, making the base-teeth interface, an entity of significance.
The synthesis of polymers starts with ethylene, (or ethene). Ethylene is obtained as a by-product of petrol refining from crude oil or by dehydration of ethanol. Ethylene molecules compose of two methylene units (CH2) linked together by a double carbon
...ooking down in such a way as to scan the entire 4m width of the road surface with 1mm resolution. This configuration allows the direct measurement of many different types of surface defects by simultaneously acquiring high resolution 3D and intensity data. Laser Crack Measurement System (LCMS) is able to work with traffic flow (speed up to 100 Km/hr) that cause massive time and accident reduction (due to not closing the road lane through inspection period) and LCMS can determine the following pavement characteristics: rutting (rut depth, rut type), Macro-texture measurements over 100 % of the lane width, 3D and 2D data to characterize cracks, pot holes, raveling, sealed cracks, joints in concrete, tinning, etc, Day and night operation, IRI and longitudinal profile, Slope and cross fall. Also, it can be concluded that Laser Devices outputs are accurate and repeatable.
Mixing sodium polyacrylate and water resulted in in a thick, clear gel that resembled ice or snow. It was sticky and wouldn’t form a shape if you held it in your hand and molded it. Adding heated water and sprinkling in poly(vinyl alcohol) to the surface of the water produced another sticky
The ingredients used in making slime contain fundamental additives that, when mixed together, cause the thick, gooey, slime every kid enjoys. Polymers are made from several smaller molecules joined by chemical bonds. The polyvinyl allows the mixture to feel slimy. Combing the polyvinyl and Borax together creates a chemical reaction. The mixture becomes cold, thicker, and elastic. This combination mixed together produces slime that is fun and safe for all ages.
Polymer-Polyethylene is partially crystalline as well as amorphous because it has crystalline and amorphous regions. Also it has linear chains so this is the simplest structure compared to a branched or network chain. This can be of an advantage to it over other types of materials as its good toughness and elongation makes it very significant in the engineering industry as it can be moulded or extruded into shape...
chains instead of hydrogen atoms. Cross-linking is another way in which the polymer can be made stronger. This involves ultraviolet radiation that bombards the polymer with electrons and formulates bonds between the molecular chains of the polymers. This is like linear polyethylene but different in that it is more impact resistant, and it has a much higher density. This allows it to be stored or be used with different chemicals that would normally cause the polymer to desolve.3 This can start to become a problem because as the polymer continues to become chemically enhanced. So the ways of dissolving and recycling the polymer become more difficult.
In addition to the bonds which hold monomers together in a polymer chain, many polymers form bonds between neighboring chains. These bonds can be formed directly between the neighboring chains, or two chains may bond to a third common molecule. Though not as strong or rigid as the bonds within the chain, these cross-links have an important effect on the polymer. Polymers with a high enough degree of cross-linking have "memory." When the polymer is stretched, the cross-links prevent the individual chains from sliding past each other. The chains may straighten out, but once the stress is removed they return to their original position and the object returns to its original
If you want to extend the life of your asphalt pavements you can use asphalt sealcoating, the process
Repair Test- This Test will be used over the whole life span of the development and will repair any errors among the way of completion.