Real Textile and Domestic Wastewater Treatment by Novel Cross-linked Microbial Fuel Cell (CMFC) Reactor

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The microbial fuel cell (MFC) is an upsurging technology in the field of bio-energy generation along with wastewater treatment. The microbial fuel cell generates energy with the help of microbes that makes it green future source of energy. In MFC, anaerobic microbes degrade organic matter and produce hydrogen ions (H+) and electrons (e-) at the anode. H+ ion diffuses through the proton exchange membrane (PEM); and e- are transported through an electrode via an external circuit to the cathode. At a cathode, e- and H+ ions combine with oxygen to form water (H2O), this results in power generation [1]. MFC has limited open circuit voltage (OCV) of 1.14 V because of the standard redox potential of NADH/ NAD+ and O2/H2O of -0.32 V and +0.82 V respectively [2]. NAD+ (Nicotinamide adenine dinucleotide) is a coenzyme found in all living cells. It is involved in redox reactions, carrying electrons in reaction during metabolism.
Double chamber MFC has been proven more efficient over single chamber MFC for treatment efficiency as removal of COD, BOD, nitrate, etc. [3, 4]. Advantage of aerobic conditions at the cathode can be taken in both either abiotic or biotic forms. Recently, bio-cathode has attracted attention of many researchers because of the increment in efficiency. In a bio-cathode, microbes act as electron mediator and also provide aerobic treatment. It as well provides a variety of terminal electron acceptors and microbes catalyze electron transfer, diminishing requirement of expensive metals like platinum and electrolyte [6]. Sun et al. [7] obtained 300% increment in power density using the bio - cathode. Hence, sequentially configured bio-anode (anaerobic treatment), and bio-cathode (aerobic treatment) assemblies may enhance per...

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