What Role Does Copper Play In Azurite Formation

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Although not known for its abundance, azurite attracts attention for its rich blue color. According to the website geology.com, this mineral is a copper carbonate hydroxide composed of Cu3(CO3)2(OH)2. Due to the increasing copper price in the 21st century, copper mines have opened back up and it is here where we see how copper plays a major role in azurite formation. When there is a reaction between the subsurface copper ores and carbon-dioxide-laden waters descending into the Earth, the azurite creation cycle begins. Imagine a stream of dissolved copper being transported into a new environment. This environment could contain water chemistry or temperature which constantly changes, thus creating a potential area for the formation of secondary
Copper, a chromophore, is the main factor granting azurite its pigmenting effect. Rich colors tend to fade away in various ways, and two of azurite’s fading factors is oxidation and weathering. Oxidation and weathering causes this mineral to shift from a blue color to a more greenish color, thus over time azurite will turn into the mineral malachite. This can be demonstrated by taking 2 [Cu(OH)2 • 2(CuCO3)] + H2O giving malachite’s chemical compound of 3 [Cu(OH)2 • (CuCO3)] + CO2
Azurite derives from the Arabic words azurite and azure where the name traces back to the Persian lazhward, an area known for another blue stone, lapis lazuli. Azurite is confined to weathered ore deposits in carbonate-rich rocks. The more crystal-like forms are in mines located in Wales and Chessy, France. Chessylite, another name for azurite, comes from the Cheesy Mine. The ore deposit of Chessy-les-Mines had an abundancy of copper in the Middle Ages until 1875, and although the mine is now closed off, much of the mined azurite has now been sold into

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