Nanocomposites Case Study

971 Words2 Pages

The substantial improvement of mechanical properties of polymer nanocomposites can be attributed to high rigidity and aspect ratio of nanoclay combined with good affinity through interfacial interaction between polymer matrix and dispersed nanoclay. It is well reported that polymer nanocomposites have excellent barrier properties against O2, CO2 and water vapor. This depends on the type of clay, i.e., compatibility between clay and polymer matrix, structure of nanocomposites and aspect ratio of clay platelets. Generally good gas barrier properties of polymer nanocomposite are archived by exfoliated clay minerals with large aspect ratio [91]. Also Rhim with his co-worker reported that water vapor transmission rate of agar/unmodified montmorillonite (Cloisite Na+) nanocomposite films is significantly lower than agar/organically modified montmorillonite (Cloisite 30B, 20A) nanocomposite [88, 89]. …show more content…

Yano with his co-worker developed polyimide/clay nanocomposite films with four different sizes of clay minerals, such as hectorite, montmorillonite, saponite and synthetic mica to understand the effect of aspect ratio on the barrier properties of nanocomposite. They found that at constant clay content (2 wt%), the relative permeability coefficient decreases with increase the length of the clay [92]. Contradictorily, Cloisite 30B is more effective in reducing the water vapor permeability of poly-lactic acid based nanocomposite films and chitosan based nanocomposite film [90, 56]. Similar results about water vapor permeability of bio-nanocomposite films based on other biopolymers, such as whey protein isolate [93-94], starch [95], soy protein isolate [96-97], poly(caprolactone) [29] and wheat gluten [98] have been

More about Nanocomposites Case Study

Open Document