Appendix 1: An Experiment On Chemistry Of Equilibrium

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Experiment 1: Introducing Equilibrium I (Appendix 1) The purpose of this experiment was to observe what happens when the reactants and productions of a reversible reaction are placed separately into a sealed container. This experiment investigated the chemistry of equilibrium using N_2 O_4 ⇋ 〖2NO〗_2. This experiment will determine if dynamic chemical equilibrium can be achieved by starting with either reactants or products. In part one of the experiment, the following conditions were: Volume lock on 1 mole of N_2 O_4 and 0 mole of 〖2NO〗_2 0.0409M of N_2 O_4 and 0M of 〖2NO〗_2 IN 24.47 L at 106.4 kPa No catalyst No unreactive gas Temperature 40°C In part two of the experiment, the following conditions were the same as part one, …show more content…

Therefore, it can be concluded that a catalyst has a major effect upon the time taken in a reversible reaction to reach equilibrium in a closed system, but does not have any effect the macroscopic properties of the system. Experiment 9: Equilibrium III – Temperature The purpose of this experiment was to see if changing the temperature has an effect upon the value of the equilibrium constant. This experiment investigated the chemistry of equilibrium using N_2 O_4 ⇋ 〖2NO〗_2. In part one of the experiment, the following conditions were: Volume lock on 1 mole of N_2 O_4 and 0 mole of 〖2NO〗_2 0.0409M of N_2 O_4 and 0M of 〖2NO〗_2 IN 24.47 L at 101.3 kPa No catalyst No unreactive gas Temperature 25°C In part two and three of the experiment, the following conditions were the same as part one, but with: 50°C (part …show more content…

It was found that at 25°C the equilibrium constant equalled to 0046750725M, at 50°C the equilibrium constant was 0.0276014706M, and at 75°C the equilibrium constant was 0.126954023M (refer to appendix 3). So, it can be concluded that with increased temperature, the equilibrium constant also increases. In addition, the increase in temperature also increased the concentration of 〖2NO〗_2, but decreased the concentration of N_2 O_4, which can also be seen in appendix 3. Experiment 12: Le Chatelier’s Principle II Pressure Effects I The purpose of this experiment was to observe the effect on an equilibrium system when the pressure acting upon it is increased. This experiment investigated the chemistry of equilibrium using N_2 O_4 ⇋ 〖2NO〗_2. In part one of the experiment, the conditions were set to: Volume lock on 1 mole of N_2 O_4 and 0 mole of 〖2NO〗_2 0.0409M of N_2 O_4 and 0M of 〖2NO〗_2 IN 24.47 L at 101.3 kPa No catalyst No unreactive gas Temperature 25°C The temperature was changed to 50°C accordingly, which caused the pressure to change to 109.8

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