Analysis Of Back Titration In Toothpaste

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The objective of this experiment is to familiarise with back titration for the determination of calcium carbonate in toothpaste and to determine the percentage of CaCO3 in toothpaste. For this experiment, an excess of HCl was added to a weighed quantity of toothpaste containing calcium carbonate. Back titration is used in this case instead of direct or forward titration as calcium carbonate is insoluble. From the two repeated back titrations that I’ve done, I’ve got an average of 23.73% of calcium carbonate in the toothpaste that I’ve tested. That is fairly near to the desired percentage of abrasive that a toothpaste should contain, which is 10-70% but preferably 20%, and with that I conclude that this experiment was a success.

Calcium Carbonate, …show more content…

It is what contributes to the cleaning power of toothpastes as it gives it the gritty texture that it has. Generally, abrasives take up to 50% of toothpastes and when used in excess will cause enamel erosion. Fluorides are also present in toothpastes to prevent cavities. A large variety of toothpastes also contain surfactants as a foaming agent, antibacterial agents, flavourants and colourants for consumer appeal and last but not least, …show more content…

They are different in a way that for direct titration, the acid is titrated directly with the base. While in back titration, the acid is added in excess and after it has reacted with the analyte, the unreacted acid is then back titrated with a known concentration of base. However, titration is not suitable for use under some circumstances and in those circumstances is when one will use back titration instead. One of which is when one of the reagents is an insoluble salt, like in this case, Calcium Carbonate. As calcium carbonate is not soluble, it cannot be dissolved into aqueous form to be pipetted into the conical flask for titration, hence, back titration is more

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