Why Some Intermolecules Melt Faster Or Take Longer To Boil?

823 Words2 Pages

David Ihim
Dr. Lowery
Pre-Ap Chemistry
30 November 2015

Don’t Flip Your Lid Research Paper Have you ever wondered why different elements have different melting and boiling points? Why some Molecules melt faster or take longer to boil? It all comes down to the forces and structure among the molecule. They are refer to as Chemical Bonding and Intermolecular or Intramolecular forces. The changes in states are due to changes in forces among the molecules rather than in those within the molecules (Zumdal 451). In this paper the effects of Chemical Bonding and Intramolecular Forces on the melting and boiling points of chemicals will be explained. These forces may involve covalent or ionic bonding, or they may involve weaker interactions usually …show more content…

The forces that exist among noble gas atoms and nonpolar molecules are called London dispersion forces (Zumdal 452). Dispersion forces are weak forces that result from temporary shifts in the density of electrons in electron cloud (Buthelezi et al. 412). Dispersion forces are named after the German-American physicist who first described them, Fritz London (Buthelezi et al. 411). The movement of electrons in the nucleus, develops a momentary non symmetrical electron distribution in noble gas atoms that creates dipolar arrangement charge for a short time. Electron distribution can occur due to the temporary formation of the dipole. That is, this instantaneous dipole that occurs accidentally in a given atom can then induce a similar dipole in a neighboring atom (Zumdal 453). The instantaneous dipole then goes to a short and weak interatomic attraction. But can be very significant for large atoms (Zumdal 453). Polarizability which indicates the ease with which the electron cloud of an atom can be distorted to give a dipolar charge (Zumdal 453). From this we can conclude large atoms that have many electrons will express a greater polarizability than small atoms. This means that the importance of London dispersion forces increases greatly as the size of the atom increases (Zumdal 453). So we can conclude molecules that do not have permanent dipole moment, their means of attracting each other is London dispersion forces. Remember that the electron in an electron cloud are in constant motion. When two molecules are in close contact especially when they collide, the electron cloud of one molecule repels the electron cloud of the other molecule, the electron density around each nucleus is, for a moment, greater in one region of each region of each clod, each molecule forms a temporary dipole when temporary dipoles are close together a weak dispersion

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