X-ray Photoelectron Spectroscopy

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X-ray Photoelectron Spectroscopy

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I. Overview

This report is a detailed study on X-ray Photoelectron Spectroscopy (XPS), a surface

characterization technique. The first question that probably comes in your mind is,

what exactly is surface characterization? Well, surface characterization is a method

which enables us to know everything about the surface in focus. Through this

method, we know the type of atoms present on the surface, the concentrations of the

atoms, the exact locations of the atoms on the surface, the bond lengths and angles of

the molecules on the surface, the strength of the bonding to the surface, and finally

the effect the surface bond will have on surface reactivity. Basically, upon

characterization, you will know the surface like the back of your hand.

The next question that might be asked would be, why do we need all this information

about a surface? The answer to this question is a lot more universal and general than

you would expect. All this information about a surface comes in handy when you are

working with or analyzing a specific surface. This method can analyze a surface as it

is received and we can use the information, or we can use it to compare after the

surface has undergone certain treatment. Some examples of this ‘treatment' are

cutting, scraping, fracturing, Ultra High Vacuum (UHV), ion beam etching, exposure

to heat, exposure to reactive gases or solutions, exposure to ion beam implant, and

exposure to UV light amongst many others. The ‘treatments' serve purposes like

exposure to bulk chemistry (UHV), cleaning surface contamination (ion beam

etching), and study of changes ...

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...l technique in the world today.

V. References

1.) Handbooks of Monochromatic XPS Spectra, Volumes 1-5, B. Vincent Crist,

published by XPS International, LLC, 2005, Mountain View, CA, USA

2.) Surface Analysis by Auger and X-ray Photoelectron Spectroscopy, ed. John T.

Grant and David Briggs, published by IM Publications, 2003, West Chester, UK

3.) Handbook of X-ray Photoelectron Spectroscopy, J.F.Moulder, W.F.Stickle,

P.E.Sobol, and K.D.Bomben, published by Perkin-Elmer Corp., 1992, Eden

Prairie, Minn, USA

4.) Wikipedia, The Free Encyclopedia, X-ray Photoelectron Spectroscopy, updated 25 Sep

2006, accessed 24 Oct, 2006.

http://en.wikipedia.org/wiki/X-ray_photoelectron_spectroscopy#Physics_of_XPS

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