Sea Water: Dolomitization

1523 Words4 Pages

Dolomitization – Question C
One of the conundrums of carbonate diagenesis is that seawater is supersaturated in dolomite, yet dolomite is rarely directly precipitated in the present day. Discuss the strengths and weaknesses of different mechanisms that have been postulated to explain dolomitization, and why it is important to understand from a hydrocarbon perspective.
Introduction
Dolomite (CaMg〖(CO_3)〗_2) is found in carbonate rocks of all ages that formed under a variety of conditions, but today it only forms in hypersaline lagoons, lakes and tidal flats. This suggests that most dolomite is secondary in origin as a result of dolomitization: the replacement of calcite or aragonite (CaCO_3) by dolomite soon after deposition or during diagenesis, generally increasing porosity. Dolomitization is therefore highly important in sedimentology and in hydrocarbon exploration but it is still not fully understood. A number of models have been proposed to explain its occurrence and why it doesn’t form everywhere, even though seawater is supersaturated with respect to dolomite (Nichols, 1999; Tucker, 2001).
Dolomitization Models
Due to dolomite’s highly ordered structure there are a number of factors that inhibit its precipitation: high ionic strength of seawater, Mg2+ hydration and low CO3- activity, even under supersaturated conditions and so certain conditions are required. These are: a sufficient supply of Mg2+ that is long lasting, an initial porosity, pressure differential for pore fluid migration and a pore fluid undersaturated in Ca2+. Therefore it is common that before dolomitization takes place the Mg:Ca ratio must increase, forcing dolomite out of solution. If these conditions are not met there will be no dolomitization and inste...

... middle of paper ...

..., G. (1999). Sedimentology & Stratigraphy (p. 355). Blackwell Science Ltd.
Potma, K., Weissenberger, J. A. W., Wong, P. K., & Gilhooly, M. G. (2001). Toward a sequence stratigraphic framework for the Frasnian of the Western Canada Basin. Bulletin of Canadian Petroleum Geology, 49(1), 37–85. doi:10.2113/49.1.37
Tucker, M. E. (2001). Sedimentary Petrology (Third., p. 262). Blackwell Science Ltd.
Whitaker, F. F., Smart, P. L., & Jones, G. D. (2004). Dolomitization: from conceptual to numerical models. Geological Society, London, Special Publications, 235(1), 99–139. doi:10.1144/GSL.SP.2004.235.01.05
Whitaker, F. F., & Xiao, Y. (2010). Reactive transport modeling of early burial dolomitization of carbonate platforms by geothermal convection. AAPG Bulletin, 94(6), 889–917. doi:10.1306/12090909075
Wright, V. P. (2009). Sedimentology Review 1 (p. 152). John Wiley and Sons.

Open Document