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Evaluating change in enthalpy
Enthalpy change question
Evaluating change in enthalpy
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Use of Enthalpy Changes of Metal Reactions
The problem: The problem that I will investigate is how to use
enthalpy changes of metal reactions to experimentally test the
reactivity series of common metals. Therefore the area that I am
looking at is reactions involving metals and the heat energy that is
evolved when these take place. In brief the reactivity series of
metals is a list in which metals are ranked according to their
reactivity, from the most reactive metals (such as Pottassium) at the
top to Gold the least reactive metal at the bottom. Therefore my
research question is “Can enthalpy changes of reaction be used to
predict the place of a metal in the metals reactivity series?”
Hypothesis:
“In reactions between various metals and the same other single
reactant, the more reactive the reacting metal the stronger will be
the bonds in the metal product formed . This will be observable
through more exothermic enthalpy changes of reaction for more reactive
metals.”
The hypothesis is the prediction which should help me to answer the
research question. If the hypothesis is proved correct through
experimentation then I can apply it to predict the place of the metals
I have investigated in the reactivity series. This will be as simple
as arranging the metals investigated in order of decreasing enthalpy
change of reaction and then comparing this list with published and
accepted data. If they match then the hypothesis will be proved
correct. If this is true then the answer to the research question will
be yes as I will then be able to use enthalpy change of reaction to
work out the place of a metal in the reactivity series without the
need to refer to a book.
The hypothesis is based on the following explanation. The enthalpy
change of a reaction is the heat evolved when a reaction takes place.
All chemical bonds hold heat energy within them. Enthalpy change of
reaction is the difference between the heat held in the bonds of
The purpose of this lab was to calculate the specific heat of a metal cylinder
So, to determine the change in enthalpy we will employ Hess’s Law of heat summation: It states that the value of DH for a reaction is the same whether it occurs directly or as a series of steps (LeMay et al, 1996). We will perform the two following reactions: Mg + 2HCl ® MgCl2 + H2 and. MgO + 2HCl ® MgCl2 + H2O, determine their enthalpy changes (DHs), and they will then be “added” to that of a given equation, the combustion of water, H2 + 1/2 O2 ® H2O
The data which was collected in Procedure A was able to produce a relatively straight line. Even though this did have few straying points, there was a positive correlation. This lab was able to support Newton’s Law of Heating and Cooling.
If I were to roughly plot a graph for the reaction, it would look like
This is expressed as Δ +ve (delta positive). If the total energy put in is less than the energy created, then the substance warms up (it is exothermic). This is expressed as Δ -ve (delta negative). I will investigate eight different alcohols using an alcohol or spirit burner, to measure the energy change during burning by measuring the change in temperature of some water held in a container.
To gain reliable results we needed a temperature rise of 50 degrees centigrade in the quickest time. possible. Then we can do it. Using the Propanol burner with different volumes of water we. tested the flame at varying distances under the calorimeter measured.
The purpose of performing this lab was to find the specific heat capacity of an unknown metal.
Specific heat capacity of aqueous solution (taken as water = 4.18 J.g-1.K-1). T = Temperature change (oK). We can thus determine the enthalpy changes of reaction 1 and reaction 2 using the mean (14) of the data obtained. Reaction 1: H = 50 x 4.18 x -2.12.
The Enthalpy Change of Different Alcohols My aim is to compare the enthalpy change of combustion of different alcohols in relation to the structure of each molecule. The enthalpy change of combustion of a fuel is a measure of the energy transferred when one mole of the fuel burns completely. In a chemical reaction, bonds must either be made or broken, this involves an enthalpy change. The formation of bonds is exothermic, energy is lost to the surrounding; on the other hand, breaking bonds is endothermic, energy is taken in. I obtain the value for the enthalpy change of each fuel by using the formula: Energy transferred from the fuel=
the iron ore to iron. In the other cases of metals the most common way
The objective of this experiment was to identify a metal based on its specific heat using calorimetry. The unknown metals specific heat was measured in two different settings, room temperature water and cold water. Using two different temperatures of water would prove that the specific heat remained constant. The heated metal was placed into the two different water temperatures during two separate trials, and then the measurements were recorded. Through the measurements taken and plugged into the equation, two specific heats were found. Taking the two specific heats and averaging them, it was then that
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Heat energy is transferred through three ways- conduction, convection and radiation. All three are able to transfer heat from one place to another based off of different principles however, are all three are connected by the physics of heat. Let’s start with heat- what exactly is heat? We can understand heat by knowing that “heat is a thermal energy that flows from the warmer areas to the cooler areas, and the thermal energy is the total of all kinetic energies within a given system.” (Soffar, 2015) Now, we can explore the means to which heat is transferred and how each of them occurs. Heat is transferred through conduction at the molecular level and in simple terms, the transfers occurs through physical contact. In conduction, “the substance
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