2.1 Introduction to Ionic Liquids Ionic liquids (ILs) are liquids composed entirely of ions. Molten salt is the term normally reserved for those systems that are liquid at high temperatures, for example NaCl (table salt is a liquid at ≈ 800 0C). Room-temperature ILs are liquid below 100˚C, have received considerable attention as substitutes for volatile organic solvents. Due to their remarkable properties, such as negligible vapour pressure, large liquidous range, high thermal stability, good ionic conductivity, high electrochemical stability, they are considered favourable medium candidates for chemical syntheses. ILs are usually categorized into four types based on their cation segment: 1) alkylammonium-, 2) dialkylimidazolium-, 3) phosphonium- and 4) N-alkylpyridiniumbased ILs (Figure 1). Ionic liquids are generally composed of a bulky organic cation, such 1-butyl-3 methylimidazolium and typically an inorganic anion such as a halide. Below are the chemical structures of some common cations and anions used to make ILs. Figure 1. Some common cations and anions used for ionic liquids ILs are designer solvents. One or both of the constituent ions can be changed in order to control physical properties. …show more content…
This means there is no "vapour" or gas sitting above the liquid. Think of the fumes that come off petrol, or the smell of coming out of an open bottle of vinegar. Petrol and vinegar have a positive vapour pressure, and you can smell the vapour that is sitting above the liquid. Well, it means there is no toxic or potentially explosive gas sitting above the solvent, unlike for example, petrol! If industrial processes can be changed to use ionic liquids, instead of the dangerous and environmentally damaging organic solvents they use now, processes will be much safer for workers, greener for the environment and easier to handle for the industrialist. Ionic liquids are also known as green
This paper describes the methods used in the identification, investigation of properties, and synthesis of an unknown compound. The compound was identified as calcium nitrate by a variety of tests. When the compound was received, it was already known to be one of twelve possible ionic compounds. The flame test identified the presence of the calcium anion in the compound. The compound tested positive for the nitrate cation using the iron sulfate test. At this point it was hypothesized that the compound was calcium nitrate. Reactivity tests and quantitative analysis comparing the unknown compound with calcium nitrate supported this hypothesis. Synthesis reactions were then carried out and analyzed.
Afterwards, we conducted crystallization to evaporate the liquid in an attempt to detect the presence of a salt. Before stating which of the potential
Procedure: Anisole (0.35mL, 0.0378mol) was obtained and placed in a pre-weighed 25 mL round bottom flask, along with 2.5 mL of glacial acetic acid and a magnetic stir bar. Then the reaction apparatus was assembled, the dry tube was charged with conc. sodium bi sulfate, the 25 mL round bottom was attached to the apparatus, and 5 mL of Br2/HBr mixture was obtained and placed in the round bottom. The reaction took place for 20 minutes. An orange liquid was obtained and placed in a 125 mL Erlenmeyer flask along with 25 mL of water and 2.5 mL of conc. Sodium bisulfate soln. The solution was then placed in an ice bath to precipitate and then the solid product was filter in a Buchner funnel. These crystals were then re-dissolved minimum amount of hot solvent (heptane) and recrystallized. Once a dry product was obtained, a melting point was established (2,4-Dibromoanisol mp 55-58 C) and percent yield was established (52%).
We have to emphasize the importance of memorizing certain names and formulas and some prefixes and suffixes that are used in building a system of nomenclature. From there on, it is a matter of applying the system to different names and formulas you meet. The summary all the ideas that will be presented in this essay help you to learn the nomenclature system.
A precipitation reaction can occur when two ionic compounds react and produce an insoluble solid. A precipitate is the result of this reaction. This experiment demonstrates how different compounds, react with each other; specifically relating to the solubility of the compounds involved. The independent variable, will be the changing of the various chemical solutions that were mixed in order to produce different results. Conversely the dependent variable will be the result of the independent variable, these include the precipitates formed, and the changes that can be observed after the experiment has been conducted. The controlled variable will be the measurement of ten droplets per test tube.
Solid A was identified to be sodium chloride, solid B was identified to be sucrose, and Solid C was identified to be corn starch. Within the Information Chart – Mystery White Solid Lab there are results that distinguishes itself from the other 4 experimental results within each test. Such as: the high conductivity and high melting point of sodium chloride, and the iodine reaction of corn starch. Solid A is an ionic compound due to its high melting point and high electrical conductivity (7), within the Information Chart – Mystery White Solid Lab there is only one ionic compound which is sodium chloride, with the test results of Solid A, it can be concluded that is a sodium chloride. Solid B was identified as sucrose due to its low electrical
Sodium chloride is the scientific name for common table salt. Some of the 40 different varieties of salt are not even edible. There are different compounds that mix with sodium to form the crystalline structure of salt. These salts are used in chemistry to create reactions.
The procedure for this experiment can be found in Inorganic Chemistry Lab Manual prepared by Dr. Virgil Payne.
Solutions are homogeneous mixtures. A chemical solution is a combination of a solvent and one or more solutes. The solvent in a solution is the majority of the solution and the solute makes up the rest of the solution. When the solvent and the solute dissolve in each other you end up with a chemical solution. Many chemical reactions are done in solutions, and solutions are also very closely related to our standard everyday lives. For example the air we breathe is a solution made up of nitrogen, oxygen, carbon dioxide and some other gasses. Because air is not a compound if you added one extra unit of oxygen it would still remain as air. Solutions can be in gaseous, liquid or solid states.
The production of synthetic detergents are an example of a standard chemical approach. If a useful substance has some undesirable properties an attempt is made to make a near copy synthetically which will perform better.
When benzoic acid paired with 1.0 M NaOH, it was observed that both compounds were soluble. Upon the addition of 6.0 M HCl into this solution, benzoic acid became insoluble. Benzoic acid was also insoluble in 1.0 M HCl. Ethyl 4-aminobenzoate was found to be insoluble in 1.0 M NaOH and soluble in 1.0 M HCl. But then, after adding 6.0 M NaOH into the test tube C (mixture of ethyl 4-aminobenzoate and 1.0 M HCl), a white powdery solid (undissolved compound) was formed. These demonstrate that both the acid and base became more soluble when they were ionized and less soluble when they were
How can placing 2 different compounds in water baths with increasing temperatures reveal whether they are ionic or covalent from their melting points?
Solvent - The component of a solution that is present in the greatest amount. It is the substance in which the solute is dissolved.
Without compounds of sodium life could not exist. In body tissues these compounds hold water, and sodium can cause death when you have a severe deficiency of sodium. Sodium compounds solutions are also found in blood. In the manufacture of chemicals and pharmaceuticals Sodium compounds are used in the production of hundreds of every day products, industry, in metallurgy, and in sodium vapor lamps. Table salt or sodium chloride is one of...
If the solid dissolved in the solvent at room temperature, then it was too soluble and that solvent could be eliminated. The acetanilide is completely dissolved in ethanol and dichloromethane, therefore eliminating them from being the suitable solvent. If the solid did not dissolve at room temperature then it was placed in the sand bath and left to boil. If the solid dissolved, it was placed in the ice bath and if crystals were observed coming out of the solution then the suitable solvent was found. The suitable solvent was water as the crystals came out once placed in the ice bath.