History Of Silicon Nitride

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1. Introduction Silicon nitride is a chemical compound of the elements silicon and nitrogen with the formula Si3N4. Silicon nitride (Si3N4) was developed in during the period of 1960-1970 in a aim to search for fully dense, high strength and high toughness materials. The particular focus for its development was to replace metals with ceramics in advanced turbine and reciprocating engine applications to give higher operating temperatures and efficiencies. Even though the final goal of a ceramic engine has never been achieved, but silicon nitride has been used in a number of industrial applications, such as engine components, bearings and cutting tools. Silicon nitride has better high temperature capabilities than most metals with adding retention of high strength and creep resistance with oxidation resistance. In accumulation, its low thermal expansion coefficient gives good thermal shock resistance comparing with other ceramic materials. It is the most thermodynamically stable compound. 2. Production Pure silicon nitride is difficult to produce as a fully dense material. This covalently bonded material does not readily sinter and cannot be heated over 1850oC as it dissociates into silicon and nitrogen at these …show more content…

Typical densities are in the range of 2300 – 2700 kg.m-3 compared with 3200 kg.m-3 for hot pressed and sintered silicon nitride. Higher densities can be achieved by HPSN and SSN methods. However, the higher density gives the materials with better physical properties and so they are used in more demanding applications. The nitridation produces only a small volume change, which means that RBSN components do not need to be machined after fabrication and complex near net shapes can be produced in a single process

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