Crystal Chemical Relationship Between Fulia And Sio4 Case Study

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Paragraph 1 Crystal chemical relationship between quartz (SiO2) and FePO4 There are a variety of crystalline SiO2 polymorphs, its basic structural units are tetrahedral, each surrounded by binding Si 4 O, Si in the center, O in the four corners; there are six silicon atoms and six oxygen atoms on the smallest ring. Many of these tetrahedral and connected by an apex angle of O, O for each two common tetrahedron, ie each O and 2 Si combined. In fact, SiO2 crystal Si and O is 1: three-dimensional network structure of the crystal of Comparative Example 2 composed. Thus, the composition is typically represented by SiO2 silica. SiO4 tetrahedral exist not only in SiO2 crystals, but also in all silicate minerals, the basic skeleton is composed of silicate colorful world. …show more content…

Where P and Fe geometry tetrahedral molecules. Phase transition occurs under high pressure, into a more dense Fe center octahedral structure. In addition, there are two rhombic structure is known and one monoclinic phase. Double dihydrate crystal form, Fe is the center of the octahedron, with two cis ligand water molecules. FePO4:SiO2 in α-quartz crystalline form SiO2 in α-quartz crystalline form , its crystal symmetry present in trigonal rhombohedron (FePO4). Helical chains making individual single crystals optically active; α-quartz converts to β-quartz at 846 K. SiO2 in β-quartz crystalline form , its crystal symmetry present in hexagonal. This pattern closely related to α-quartz (with an Si-O-Si angle of 155°) and optically active; β-quartz converts to β-tridymite at 1140 K. SiO2 in β-quartz crystalline form Paragraph 2 The symmetry relationship between the FePO4 polymorphs and dependence on

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