Redox Flow Batteries: A Load-Leveling Energy-storage System

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Energy plays a critical role in the society of today, from the lights in your room to the medical equipment in the city hospital, human life depends greatly on energy production. Between the energy crisis of the 70s and the increasing carbon emissions in the air, renewable and alternative energy has seen increasing demand in research. While solar and wind plants are effective, they face challenges in their inability to hold excess power to be evenly distributed when required during maximum and non-maximum peak hours. To address this issue, energy-storage devices, such as secondary batteries and hydrogen fuel cells have undergone research, testing, and eventual commercial use. Among these energy-storage devices is the Redox Flow Battery (RFB), a secondary battery with a simple but productive design. While commercialisation and design on a large-scale has been hit and miss for most systems, the Redox Flow Battery still provides an effective energy storage tool for now and the future.

To begin with, the Redox Flow Battery follows a non-complex design; most RFBs contain a positive and negative half-cell that is separated by an ion-exchange membrane. Each half-cell contains its own electrode to allow energy to flow through the system in the form of an electrolyte solution, which stores the energy, that is pumped to and from separate electrolyte storage tanks for

Figure 1 – Redox Flow Battery Design

each half-cell. True to its name, oxidation reactions occur during charging and reduction reactions occur during discharging in the positive half-cell, while the reverse occurs in the negative half-cell. A major advantage to the RFB compared to conventional batteries is the use of fully soluble redox couples and electrodes, removing th...

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... system for load-leveling applications. Although only the all-vanadium system has met required energy efficiencies and environmental concerns, the redox couples in the RFB design are readily changed and modified. Reliable energy-storage systems such as RFBs will make renewable energy generation more attractive and grab a greater portion of overall energy production in the future.

References

Chakrabarti, Mohammed, Hajimolana S., Mjalli F., Saleem M., and Mustafa I. Redox Flow Battery for Energy Storage. Arabian Journal for Science & Engineering [Online] April 2013, p723-739. Academic Search Complete. (accessed April 12, 2014)

Weber, Adam, Mench M., Meyers J., Ross P., Gostick J., Liu Q. Redox flow batteries: a review. Journal of Applied Electrochemistry [Online] October 2011, p1137-1164. Academic Search Complete. (accessed April 15, 2014)

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