Precision and Cleanliness in Volumetric Glassware Calibration

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As an analyst, accurate measurements are done with the help of volumetric glassware’s, like buret and pipet. Volumetric glassware are containers that have been calibrated at specific temperature to deliver or contain very precise amount of liquid. In order to ensure the accuracy and precision of the glassware’s then a calibration must be done. The assumption of volume for volumetric glassware is dependent on the cleanliness of the surface. Although accuracy is more important in TD (to deliver) glassware there should still be considerations for the messy and unpleasant substances on the surface of the TC (to contain) glassware. Soaking of the glassware for too long with detergent is not also advisable since it will likely develop a rough area …show more content…

Check if there are any leaks especially around the stopcock, the valve at the bottom of the buret. When it comes to calibration, it is calibrated by transferring water into an Erlenmeyer flask and weighing it using an analytical balance. This is done for two (2) trials, each with varying amounts of water. Erlenmeyer’s mass is pre-recorded before transferring water from the buret. The volume delivered by the buret is considered the apparent, which means evident, volume. Before starting another set, the flask should be clean and dry to avoid any error. The water inside the flask will add the volume to be transferred thus making the mass of water higher than what it should really be. The mass of water obtained thru weighing by difference would then be multiplied to the buoyancy of water at the recorded temperature which will then be the corrected mass of the water. The corrected mass of the water is then divided by the density of the water, at the same temperature, and will be considered as the true mass. Correction value can be obtained by solving for the difference between the true volume and the apparent volume. Some of the correction value computed are negative and it only means that there is an error that occurred. One of the possible errors in most volumetric glassware’s is reading the wrong volume. Volume must be read based on the lower meniscus at eye

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