The Effect Of Alloying Elements On Alloy Sacrificial Anode

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The effect of alloying elements on aluminium alloy sacrificial anode was also studied and it was found that the alloying element which have large potential difference from aluminium resulted in alloys with potentials more anodic than unalloyed aluminium. Mercury, the potential of which differs most greatly from that of aluminium, caused a maximum effect on aluminium potential. Effect of some alloying elements on aluminium alloy as sacrificial anode is given below:
1. Magnesium: The solubility of magnesium is about 1.5% at room temperature. Alloying with magnesium has shown improved cathodic protection characteristic and optimum concentration is of greater importance in attaining the desired properties, otherwise excess magnesium reacts with aluminium to form the anodic constituents Mg2Al3 which promotes inter-granular corrosion. The addition of …show more content…

Nickel: Nickel increases strength to a modest extent but reduces ductility. The addition of nickel imparts resistance to softening at higher temperature but gives poor casting and machining characteristics. The addition of nickel to Al-Cu and Al-Si type alloy system improves hardness and strength at elevated temperature. It improves resistance to corrosion in powder metallurgy products.
6. Iron: It reduces cathodic protection characteristics by increasing pitting corrosion because it forms FeAl3, when present at higher concentrations. But this effect can be reduced by addition of 1.25% manganese. The presence of iron (max. of 0.1%) is beneficial, especially in improving the galvanic efficiency in case of Al-Zn-In alloys. It forms a coarse constituent with aluminium and other alloying elements such as copper, nickel, manganese and silicon thus reducing ductility. It also reduces the strength and impairs corrosion resistance and fatigue resistance properties.
7. Chromium: It generally improves the corrosion resistance when added 0.15-0.25% in amount to Al-Zn-Cu-Mg alloy and reduces the stress corrosion cracking

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