Chemtrek Hard Water

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Defined in Chemtrek as “The presence of the dissolved divalent cations Ca2+ and Mg2+. . . (which) gives natural waters chemical properties”, hard water has always been a curse to both animals and man 1 . It promotes scale, the buildup of magnesium and calcium to the point where a rock-like substance forms in household and industrial pipes, disrupts natural habitats and reproductive cycles of fresh water fish, and causes many health-related problems in humans 2 . To avoid such problems, it is important to understand ways that commercial businesses and homeowners can test for hard water. This experiment examines two possible methods of testing water hardness. They include: AA spectroscopy, which measures a water sample's absorption …show more content…

My hypothesis stated that the water from Little Chickies Creek would be the hardest because it is located by several limestone quarries, which deposit calcium and magnesium into creeks and streams 5 . I proposed that the water from Stone Valley Lake would have the second highest levels of calcium and magnesium because it is also in an area with a lot of limestone. I also proposed that the water from the pond on Orr Avenue would be the third hardest since the surrounding area has some limestone. However, I presumed that the water from the Allegheny River would be the softest because it has been affected by Acid Mine Drainage, a process where run-off from coal mining seeps into water sources and raises its acidity and pH, therefore lowering its hardness 6 …show more content…

With respect to each member's sample, I felt that the precision of the AA spectroscopy and EDTA results were not that precise because the values were far apart from each other. For instance, my data had AA spectroscopy and EDTA titration values of 167.31ppm and 240ppm respectively. However, I observed that the lake's and pond's values were precise when compared to each other because they had the same EDTA titration values and nearly identical AA spectroscopy values. (Refer to Chart 3 in Results)

I also determined that the accuracy of my data may have been affected by factors such as location of the water sample and incorrect measurements. To determine the accuracy for this experiment, I calculated the experimental error for the AA spectroscopy values in order to see how the concentration of my water sample differed from the concentration values provided by the chemistry department. The following are calculations for the experimental error of calcium and magnesium concentrations:

Experimental error = observed value – accepted value X

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