Microrganisms Functioning to Neutralize Toxic Wastes in Our Environment

1368 Words3 Pages

The presence of radionuclides and heavy metals in our surroundings has become the most serious environmental concern. These contaminants or pollutants fail to degrade on their own over time and must be removed or neutralized. Microorganisms act as natural catalysts in the process of transformation of toxic metals into non-toxic ones. This is why there is an increased interest in the understanding of microbiological processes which help in remediation of these toxic wastes from the environment (Francis 1990).

Microorganisms basically work by mobilization and immobilization of heavy metals and radioactive wastes. Mobilization include processes such as methylation of wastes and thus making them volatile substances, chelation of metals to certain ligands which help to neutralize their toxic effects, autotrophic and heterotrophic leaching.

Alternatively, immobilization occurs as an outcome of sorption to cell components, transport into cells, precipitation as insoluble compounds etc. (Gharieb et al. 1998), (Sayer et al. 1997).

In nature, the radioactive wastes and heavy metals can be present in a number of forms such as oxides, superoxides, peroxides, sulphates, nitrates, citrates, carbonates etc. Microorganisms change these forms or states of toxic substances into less toxic or non toxic states. They carry out these transformations due to their sensitivity towards presence or absence of free electrons. Under aerobic conditions, the microorganisms direct oxygen to act as electron acceptor and under anaerobic conditions the suphate group, nitrate group, phosphate group or carbonate group etc. take up the electrons (Francis 1990).

The process of microbial transformation of radionuclides and heavy metals is considered important becau...

... middle of paper ...

...a (SRB).

3.2.4 Biotransformation of Technetium

Technetium can exist in a large number of oxidation states such as Tc, Tc(III), Tc(IV), Tc(V), Tc(VI) and Tc(VII). It is produced in large amounts during the nuclear fission reaction of U235 and during production and testing of nuclear weapons (Yoshihara 1996). Technetium can precipitate out from the solution by oxidation as well as reduction reactions. During oxidation of Tc(III) and Tc(IV), hydrolysis reaction takes place which gives out precipitates of Technetium from the solution.

Also, Sulphate Reducing Bacteria and many other fermentatie bacteria can bring about the anaerobic reduction of Tc(VII) to Tc(IV) which can easily separate out as precipitates in the solution (Lyalikova and Khiznyak 1996, Pignolet et al. 1989, Tagami and Uchida 1996, Wildung et al. 2000, Francis et al. 2002, Khijniak et al. 2003).

More about Microrganisms Functioning to Neutralize Toxic Wastes in Our Environment

Open Document